Instantaneous hydrolysis of nerve-agent simulants with a six-connected zirconium-based metal-organic framework.
نویسندگان
چکیده
A nerve-agent simulant based on a phosphate ester is hydrolyzed using a MOF-based catalyst. Suspensions of MOF-808 (6-connected), a material featuring 6-connected zirconium nodes, display the highest hydrolysis rates among all MOFs that have been reported to date. A plug-flow reactor was also prepared with MOF-808 (6-connected) as the active layer. Deployed in a simple filtration scheme, the reactor displayed high hydrolysis efficiency and reusability.
منابع مشابه
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ورودعنوان ژورنال:
- Angewandte Chemie
دوره 54 23 شماره
صفحات -
تاریخ انتشار 2015